Regioselective double dehydrative cyclization route to construct polyheterocyclic skeletons consisting of 2,3-dihydroquinazolin-4(1H)-ones and 1,2-dihydropyrrolo[1,2-a]pyrazines
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초록

The Sc(OTf)3-catalyzed reaction of 2-aminobenzamide with N-substituted pyrrole-2-carboxaldehyde proceeded well to give a tetracyclic skeleton consisting of dihydroquinazolin-4-one and 1,2-dihydropyrrolo[1,2-a]pyrazine via regioselective double cyclodehydrations where two heterocyclic rings (quinazolinone and pyrazine) were sequentially constructed through the formation of three C-N bonds.

제목
Regioselective double dehydrative cyclization route to construct polyheterocyclic skeletons consisting of 2,3-dihydroquinazolin-4(1H)-ones and 1,2-dihydropyrrolo[1,2-a]pyrazines
저자
구도희Song, SeoyoungKim, Ikyon
DOI
10.1039/d5ob00580a
발행일
2025-07
저널명
Organic and Biomolecular Chemistry
23
27
페이지
6589 ~ 6602