Graphene Nanoribbon/Carbon Nanotube Hybrid Hydrogel: Rheology and Membrane for Ultrafast Molecular Diafiltration
  • Kim, J.Y.
  • Choi, Y.
  • Choi, J.
  • Kim, Y.-J.
  • Kang, J.
  • 외 5명
Citations

WEB OF SCIENCE

5
Citations

SCOPUS

26

초록

Hybrids based on carbon nanotubes (CNTs) and graphene nanoribbons (GNRs) are expected to have synergistic effects for various applications. Herein, we demonstrate a simple one-pot synthesis of a CNT/GNR hybrid material by adjusting the oxidation and unzipping conditions of multi-walled CNTs (MWNTs). The MWNT/graphene oxide nanoribbon (GONR) hybrid was dispersed in various solvents, particularly showing the hybrid hydrogel phase in water at a concentration of 40 mg mL-1. The MWNT/GONR hydrogel exhibited shear-thinning behavior, which can be beneficial for coating a large-area MWNT/GONR layer onto a polymeric porous support by using a scalable slot-die coater. The MWNT/GONR membrane exhibited an outstanding nanofiltration performance, with a molecular weight cutoff of 300 Da and a dye/salt diafiltration performance with a separation factor of 1000 and a water flux of 367.8 LMH, far surpassing the upper bound of diafiltration performance of the existing membranes. © 2022 American Chemical Society

키워드

diafiltrationgraphene nanoribbonhybrid coatinghydrogelmembraneNANOFILTRATION MEMBRANENF MEMBRANEOXIDEULTRAFILTRATIONMECHANISMSSEPARATION
제목
Graphene Nanoribbon/Carbon Nanotube Hybrid Hydrogel: Rheology and Membrane for Ultrafast Molecular Diafiltration
저자
Kim, J.Y.Choi, Y.Choi, J.Kim, Y.-J.Kang, J.Kim, J.P.Kim, J.H.Kwon, O.Kim, S.-S.Kim, D.W.
DOI
10.1021/acsami.1c24733
발행일
2022-03
유형
Article
저널명
ACS Applied Materials and Interfaces
14
9
페이지
11779 ~ 11788