Thermally-induced pore size tuning of multilayer nanoporous graphene for organic solvent nanofiltration
- Authors
- Kang J.; Choi Y.; Kim J.P.; Kim J.H.; Kim J.Y.; Kwon O.; Kim D.I.; DAEWOO KIM
- Issue Date
- Nov-2021
- Publisher
- ELSEVIER SCIENCE BV
- Keywords
- Pore tuning; Diafiltration; Graphene; Membrane; OSN
- Citation
- Journal of Membrane Science, v.637, pp 119620-1 - 119620-8
- Journal Title
- Journal of Membrane Science
- Volume
- 637
- Start Page
- 119620-1
- End Page
- 119620-8
- URI
- https://yscholarhub.yonsei.ac.kr/handle/2021.sw.yonsei/6396
- DOI
- 10.1016/j.memsci.2021.119620
- ISSN
- 0376-7388
- Abstract
- Graphene-based materials have been used for fabricating organic solvent nanofiltration membranes due to their
excellent mechanical properties and chemical stability in organic solvents. However, graphene membranes
exhibit low organic solvent permeation properties due to the large molecular size of the organic solvent molecules
and their strong interactions with the graphene surface. Herein, a nanoporous graphene membrane was
fabricated to enhance organic solvent permeation. Nanopores were generated on the basal plane of graphene by
rapid thermal annealing of graphene oxide. The size of the nanopores was also tuned from micropores to
nanopores by adjusting the activation temperatures. The optimized nanoporous graphene membrane showed
ultrafast isopropyl alcohol permeance up to 295 Lm? 2h? 1bar? 1 and a sharp molecular weight cut-off of 616 Da.
The membrane showed excellent stability and diafiltration performance under cross-flow filtration with a separation
factor of around 1000 for dye molecules mixed in isopropyl alcohol.
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Collections - College of Engineering > Chemical Engineering > 1. Journal Articles
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